Decisive role of heavy-atom orientation for efficient enhancement of spin–orbit coupling in organic thermally activated delayed fluorescence emitters

نویسندگان

چکیده

A heavy-atom field effect (HAFE) is discovered in red TADF emitters bearing Br atoms donor fragment. Depending on the position of heavy atoms, HAFE can either accelerate or inhibit reverse intersystem crossing.

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ژورنال

عنوان ژورنال: Journal of Materials Chemistry C

سال: 2022

ISSN: ['2050-7526', '2050-7534']

DOI: https://doi.org/10.1039/d2tc01729f